For \(\mathbf{u}\text{,}\) we need to find coefficients \(a_1\) and \(a_2\) such that \(a_1\mathbf{v}_1+a_2\mathbf{v}_2=\mathbf{u}\text{.}\) To do this we need to solve the linear combination equation:
\begin{equation*}
a_1\begin{bmatrix}-2\\-3\\4\end{bmatrix}+a_2\begin{bmatrix}2\\3\\2\end{bmatrix}=\begin{bmatrix}2\\3\\5\end{bmatrix}.
\end{equation*}
Now we write the corresponding augmented matrix and reduce it to reduced row echelon form.
\begin{equation*}
\left[\begin{array}{cc|c}
-2\amp 2\amp 2\\-3\amp 3\amp 3\\4\amp 2\amp 5
\end{array}\right]
\xrightarrow{\text{RREF}}
\left[\begin{array}{cc|c}
1\amp 0\amp 1/2\\0\amp 1\amp 3/2\\0\amp 0\amp 0
\end{array}\right].
\end{equation*}
Hence, \(a_1=\frac{1}{2}\text{,}\) \(a_2=\frac{3}{2}\text{,}\) and we can express \(\mathbf{u}\) as a linear combination of \(\mathbf{v}_1\) and \(\mathbf{v}_2\) as follows:
\begin{equation*}
\frac{1}{2}\begin{bmatrix}-2\\-3\\4\end{bmatrix}+\frac{3}{2}\begin{bmatrix}2\\3\\2\end{bmatrix}=\begin{bmatrix}2\\3\\5\end{bmatrix}.
\end{equation*}
Observe that because vector \(\mathbf{u}\) is a linear combination of \(\mathbf{v}_1\) and \(\mathbf{v}_2\text{,}\) \(\mathbf{u}\) is the diagonal of a parallelogram whose sides are scalar multiples of \(\mathbf{v}_1\) and \(\mathbf{v}_2\text{.}\) As such, \(\mathbf{u}\) lies in the same plane as \(\mathbf{v}_1\) and \(\mathbf{v}_2\text{,}\) as illustrated below.

For \(\mathbf{w}\text{,}\) we need to solve the following vector equation:
\begin{equation*}
a_1\begin{bmatrix}-2\\-3\\4\end{bmatrix}+a_2\begin{bmatrix}2\\3\\2\end{bmatrix}=\begin{bmatrix}5\\5\\1\end{bmatrix}.
\end{equation*}
Writing the equation in augmented matrix form and applying elementary row operations gives us the following reduced row echelon form:
\begin{equation*}
\left[\begin{array}{cc|c}
-2\amp 2\amp 5\\-3\amp 3\amp 5\\4\amp 2\amp 1
\end{array}\right]
\xrightarrow{\text{RREF}}
\left[\begin{array}{cc|c}
1\amp 0\amp 0\\0\amp 1\amp 0\\0\amp 0\amp 1
\end{array}\right].
\end{equation*}
We conclude that there are no solutions, and \(\mathbf{w}\) is not a linear combination of \(\mathbf{v}_1\) and \(\mathbf{v}_2\text{.}\)
Geometrically, this means that \(\mathbf{w}\) is not the diagonal of any parallelogram whose sides are scalar multiples of \(\mathbf{v}_1\) and \(\mathbf{v}_2\text{.}\) Thus, \(\mathbf{w}\) does not lie in the plane determined by \(\mathbf{v}_1\) and \(\mathbf{v}_2\text{.}\)